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Refinery Off-Gas Processing

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Refinery Off-Gas Processing

Compositions and Contaminants in ROG

Compositions ROG Mole%

H2O      

 0.48

Nitrogen

11.19

CO      

 0.43

CO2   

0.03

H2       

 11.25

Ethylene

21.74

Ethane  

14.48

Propene

 2.96

Propane 

0.56

C4+

 1.06

Total

100

Mol wt

21.95

Contaminants in  ROG wppm

Oxygen 

1000

Acetylene

470

RSH

5

RSR

4

COS

10

Arsine

100 wppb

Nitride 

7

Nitriles

7

Hg

10 wppb

NOx

50

Butadiene

2

  

Carbonyls are generated in the Steam Crackers during the production of base petrochemicals.

The impurities include CO2, H2S, COS, RSH, acetylenes, dienes, NH3, O2, NOx, HCN, PH3, Hg and arsine. Proper placement and sequencing of the contaminant removal equipment is critical to ensure the most economical and reliable approach to contaminant removal.

Carbonyls are generated in the Steam Crackers during the production of base petrochemicals.